The administrative, political and religious centre of Bolivia during Spanish rule, is still officially the capital. A UNESCO World Heritage Site, Sucre is Bolivia's most refined a beautiful city, a masterpiece of immaculately preserved colonial architecture, full of elegant churches, mansions and museums. It’s also the market centre for the deeply traditional Quechua-speaking communities of the surrounding mountains.
Car
Day 2 — Sucre → Potosì
PotosÃ, a UNESCO World Heritage Site, is the highest city in the world, 4100 m above sea level, on a desolate, windswept plain. The city owes its existence to Cerro Rico (Rich Mountain), the richest source of silver the world had ever seen: its mines turned Potosà into one of the world’s wealthiest and largest cities. In the early seventeenth century its population was 160,000, far bigger than contemporary Madrid, and equal in size to London. However, this wealth was achieved at the expense of the lives of millions of indigenous forced labourers and African slaves. Estimates of the total number who died over three centuries of colonial mining in Potosà run as high as nine million. Today it's a repository of colonial art and architecture.
Car
Day 4 — Colchani → Uyuni
on the bleak southern Altiplano 212 km southwest of PotosÃ, the town of Uyuni, 3.668 m asl, is the convenient (and nothing else) jumping-off point for touring the remote and beautiful scenery of the surrounding region.